Intermolecular Charge-Transfer Spectra. I. Halogen-Aromatic Complexes
نویسندگان
چکیده
منابع مشابه
Photo-induced Intermolecular Charge Transfer in Porphyrin Complexes
Optical excitation of the sequential supermolecule H2P −ZnP −Q induces an electron transfer from the free-base porphyrin (H2P ) to the quinone (Q) via the zinc porphyrin (ZnP ). This process is modeled by equations of motion for the reduced density matrix which are solved numerically and approximately analytically. These two solutions agree very well in a great region of parameter space. It is ...
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The role of charge transfer in halogen bonding is the subject of an ongoing debate and controversy. It is clear from experimental data that charge transfer occurs in halogen bonds, but its contribution to the energetics of the interaction can be evaluated only computationally. Since the charge transfer is not a physically well-defined property, there are multiple computational approaches, which...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1953
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.26.441